期刊
JOURNAL OF CHEMICAL PHYSICS
卷 130, 期 13, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.3094321
关键词
molecule-photon collisions; organic compounds; photodissociation; photoexcitation
资金
- U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences [DE-AC02-06CH11357]
- University of Chicago/Argonne Strategic Collaborative Initiative
The photodissociation of i-propyl iodide in the A absorption band was studied by using velocity map ion imaging following excitation between 304 and 253 nm. The translational energy distributions and translational energy dependence of the angular distributions of the I P-2(3/2) and P-2(1/2) photofragments were recorded as a function of the photodissociation wavelength. These distributions are used to decompose the i-C3H7+I P-2(3/2) channel into contributions from two processes: Excitation to the (3)Q(0)(+) state followed by crossing onto the (1)Q(1) surface, and direct excitation to the (3)Q(1) surface followed by dissociation on that surface. As in the case of methyl iodide, the former process dominates; the latter process contributes only in the red wing of the absorption band, with its contribution peaking at similar to 287 nm with an absorption of similar to 1% of the band maximum. The data for the i-C3H7+I-* P-2(1/2) channel display a smooth behavior across the full energy range of the present study, and are consistent with direct excitation to the (3)Q(0)(+) surface followed by dissociation on that surface.
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