4.7 Article

Closed-form expressions of the chemical potential for integral equation closures with certain bridge functions

期刊

JOURNAL OF CHEMICAL PHYSICS
卷 129, 期 23, 页码 -

出版社

AMER INST PHYSICS
DOI: 10.1063/1.3041709

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chemical potential; integral equations

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  1. Sanofi-Aventis Deutschland GmbH
  2. Fonds der Chemischen Industrie
  3. Adolf-Messer-Stiftung

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A general, path-independent expression is derived for the excess chemical potential of integral equation closure approximations that contain a bridge function which depends on a renormalized indirect correlation function. Closed-form results are obtained for various cases, among them a partial series expansion of the hypernetted chain closure.

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