期刊
JOURNAL OF CHEMICAL EDUCATION
卷 91, 期 6, 页码 889-891出版社
AMER CHEMICAL SOC
DOI: 10.1021/ed400824g
关键词
First-Year Undergraduate/General; Laboratory Instruction; Organic Chemistry; Hands-On Learning/Manipulatives; Alcohols; Alkanes/Cycloalkanes; IR Spectroscopy; Quantitative Analysis
资金
- Wilmington College
Ethanol is the primary oxygenate in gasoline in the United States. Gasoline containing various percentages of ethanol is readily available in the market place. A laboratory experiment has been developed in which the percentage of ethanol in hexanes can easily be determined using the O-H and alkane C-H absorptions in an infrared spectrum. Standard solutions of ethanol mixed with hexanes are prepared, and their infrared spectra collected. The areas under the O-H and C-H absorptions are used to prepare a standard curve, which is used to determine the percentage of ethanol. Results for the analysis of ethanol in gasoline from this model ethanol/hexanes calibration system compare favorably to advertised values, as well as to values determined by water extraction.
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