3.9 Article

Syntheses, Structures and Luminescent Properties of Zinc(II) and Cadmium(II) Complexes With the Ditopic Ligand 1,3-Bis(imidazol-1-ylmethyl)benzene

期刊

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
卷 42, 期 4, 页码 416-422

出版社

SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s10870-011-0257-6

关键词

Coordination polymer; Bis(imidazole) ligand; Crystal structure; Luminescence

资金

  1. National Natural Science Foundation of China [20971004]
  2. Outstanding Youth Foundation of Education Commission of Anhui Province [2010 SQRL108ZD]
  3. Grants-in-Aid for Scientific Research [23655178] Funding Source: KAKEN

向作者/读者索取更多资源

Three new complexes, namely [Zn(mbix)(SO4)]center dot CH3OH (1), Cd(mbix)(2)(NO3)(2) (2) and [Cd(mbix)(2)(H2O)(2)]center dot(NO3)(2) (3), have been obtained by reactions of flexible bidentate ligand 1,3-bis(imidazol-1-ylmethyl)benzene (mbix) with corresponding zinc(II) and cadmium(II) salts. The structures of these complexes have been determined by the X-ray single crystal diffraction analysis. Complex 1 features a 2D wavy network with (4,4) topology. Complex 2 has a 2D grid network with left- and right-handed helical chains, while complex 3 exhibits twofold parallel interpenetration structure. The differences of three complexes demonstrate that the coordination geometry of metal ions and the ratio of reactants have a great impact on the structure of the supramolecular architectures. The luminescent properties of three complexes are also investigated.

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