期刊
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
卷 39, 期 4, 页码 229-240出版社
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s10870-008-9474-z
关键词
Porphyrin; Coordination polymers; Structural motif; Topological control
资金
- University of Nebraska-Lincoln
In this review, we classify 1D, 2D, and 3D structural motifs found in porphyrinic coordination polymers assembled from 5,10,15,20-tetrapyridylporphyrin (TPyP) and its derivatives. The classifications are based on dimensionality, metal-to-porphyrin linkage, porphyrin type, and metal-to-porphyrin ratio. 1D porphyrin polymers often share the same connectivity (or structural motifs) with analogous 2D and 3D polymers. We identify interrelationships among 1D, 2D, and 3D coordination polymers and examine the connectivity of such interrelated structures. We also discuss the broad similarities and differences of the synthetic methods of all structures presented here.
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