期刊
JOURNAL OF CHEMICAL AND ENGINEERING DATA
卷 59, 期 11, 页码 3912-3919出版社
AMER CHEMICAL SOC
DOI: 10.1021/je500801w
关键词
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资金
- National Natural Science Foundation of China [51276010]
- National Basic Research Program of China [2010CB227304]
According to the structure feature of the absorption power cycle, three binary systems 1,1,1,3,3-pentafluoropropane (R245fa) + N,N-dimethylacetamide (DMAC), 1,1,1,3,3,3-hexafluoropropane (R236fa) + DMAC and R236fa + dimethyl ether diethylene glycol (DMEDEG) were identified as potential working fluids. The vaporliquid equilibrium (VLE) data of these three systems were measured over a temperature range of 293.15 K to 353.15 K and a pressure range of 20 MPa to 800 kPa. The five-parameter nonrandom two-liquid (NRTL) model was used to fit the experimental data. The average relative deviations in the pressure between the experimental and calculated data for R245fa + DMAC, R236fa + DMAC and R236fa + DMEDEG were 1.51 %, 1.61 % and 1.25 %, respectively, and the maximum relative deviations were 3.21 %, 3.52 % and 2.96 %, respectively. The calculated data were in good agreement with the experimental data. The three working fluids all displayed negative deviations from Raoults law, and the deviations decreased in the following order: R236fa + DMEDEG > R236fa + DMAC > R245fa + DMAC.
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