4.2 Article

Adsorption of Copper Ions and Methylene Blue in a Single and Binary System on Wheat Straw

期刊

JOURNAL OF CHEMICAL AND ENGINEERING DATA
卷 54, 期 12, 页码 3229-3234

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AMER CHEMICAL SOC
DOI: 10.1021/je900220q

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资金

  1. National Natural Science Foundation of China [J0830412]
  2. China Postdoctoral Science Foundation [20070420811]
  3. Natural Science Foundation of Henan Province

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A natural wheat straw was used as adsorbent for removal of copper and methylene blue (MB) from aqueous solution. A batch system was applied to Study the behavior of Cu2+ and MB adsorption in single and binary systems oil wheat straw In the single Systems, there was no significant difference in the quantity of MB adsorbed onto wheat straw within a pH range of 4.0 to 10.0. But for Cu2+, the optimal pH is about 5. Kinetic studies indicate that Cu2+ and MB adsorption oil the wheat straw follows the Elovich equation. The Cu2+ adsorption isotherm follows the Langmuir and Redlich-Peterson models, while MB adsorption follows the Redlich-Peterson isotherm The adsorption capacities of Cu2+ and MB at 273 K and pH 5 are (7.05 and 60.66) mg.g(-1) respectively In the binary system, Cu2+ and MB exhibited competitive adsorption The adsorption of Cu2+ or MB is considerably reduced with all increasing concentration of the other The quantity of Cu2+ adsorbed is more strongly influenced by MB due to the higher affinity of wheat straw for the latter. As wheat straw is easily obtained and cheap, it will be promising for removal of metal ions and dyes

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