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Densities and Viscosities of Binary Mixtures of Acetic Acid with Acetic Anhydride and Methenamine at Different Temperatures

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JOURNAL OF CHEMICAL AND ENGINEERING DATA
卷 53, 期 12, 页码 2892-2896

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AMER CHEMICAL SOC
DOI: 10.1021/je8003782

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Densities and viscosities of the binary mixtures of acetic acid + acetic anhydride have been measured at temperatures from (293.15 to 338.15) K and atmospheric pressure over the whole concentration range of compositions. The excess molar volume (V(E)) and viscosity deviation (Delta(n)) were calculated from the experimental data and correlated by the Redlich-Kister equation. In addition, densities and viscosities of methenamine + acetic acid solutions were measured, and the results were represented by third-order and fourth-order (empirical) polynomials in terms of mole fraction of methenamine.

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