期刊
JOURNAL OF CATALYSIS
卷 306, 期 -, 页码 38-46出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2013.06.006
关键词
Metal-organic framework; Cross-dehydrogenative; C-H activation; Heterogeneous catalyst; Cu-2(BPDC)(2)(BPY)
资金
- Viet Nam National Foundation for Science and Technology Development - NAFOSTED [104.99-2012.25]
A crystalline porous metal-organic framework Cu-2(BPDC)(2)(BPY) was synthesized and characterized by Xray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), Fourier transform infrared (FT-IR) spectra, atomic absorption spectrophotometry (AAS), hydrogen temperature-programmed reduction (H-2-TPR), and nitrogen physisorption measurements. The Cu-MOF could be used as an efficient heterogeneous catalyst for the copper-catalyzed cross-dehydrogenative coupling reaction of ethers with 2-carbonyl-substituted phenols. The Cu-2(BPDC)(2)(BPY) exhibited significantly higher catalytic activity than that of other Cu-MOFs such as Cu-3(BTC)(2), Cu(BDC), and Cu(BPDC). The Cu-MOF also offered advantages over several copper salts such as CuCl2, CuCl, , Cu(NO3)(2), and Cu(OAc)(2) in terms of the catalytic activity as well as the catalyst reusability. To the best of our knowledge, the cross-dehydrogenative coupling reaction of ethers with 2-carbonyl-substituted phenols via C-H activation under oxidative conditions using a heterogeneous catalyst was not previously mentioned in the literature. (C) 2013 Elsevier Inc. All rights reserved.
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