期刊
JOURNAL OF CATALYSIS
卷 308, 期 -, 页码 282-290出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2013.08.019
关键词
Heterogeneous catalysis; Methanation reaction; Mass-selected nanoparticles
资金
- Danish National Research Foundation's Center for Individual Nanoparticle Functionality [DNRF54]
Mass-selected Ru nanoparticles were deposited onto planar SiO2 support and their capability for the methanation reaction investigated. The catalytic activity for the methanation reaction at 100 mbar under hydrogen rich conditions (1:99 CO/H-2 ratio) was measured as a function of particle size. We found that the Turnover Frequency increased with nanoparticle diameter in the range 4-10 nm. As the TOF decreases over reaction repetition, we investigated the possible reasons and ruled out carbon deposition as a cause for activity loss. As no particle sintering was observed, we invoked surface restructuring as a possible cause. (C) 2013 Elsevier Inc. All rights reserved.
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