期刊
JOURNAL OF CATALYSIS
卷 291, 期 -, 页码 110-116出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2012.04.015
关键词
MCM-41; One-pot; Domino; Ruthenium; NHC pincer ligand; Supported catalysts; Catalyst recycling
资金
- Direccion General de Investigacion Cientifica y Tecnica of Spain [MAT2011-29020-C02-02, CSD-0050-MULTICAT]
Supported ruthenium complexes based on electron-rich (NHC)NN-pincer-type ligands selectively catalyze the formation of substituted amines from nitroaromatics and carbonyl compounds through a series of consecutive steps which involves the reduction of nitro group to amine, the formation of an imine or iminium ion intermediate, followed by in situ reduction to an alkylated amine of higher order in a single operation. Solid complexes result active and recyclable catalysts and no deactivation was observed after repeated recycling. (C) 2012 Elsevier Inc. All rights reserved.
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