期刊
JOURNAL OF CATALYSIS
卷 275, 期 1, 页码 70-77出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2010.07.017
关键词
Heteropolyacids; Enantioselective catalysis; Immobilized catalysts
资金
- Spanish Ministerio de Ciencia e Innovacion [CTQ2008-05138, CSD2006-0003]
- Diputacion General de Aragon
- European Regional Development Funds
- Agencia Espanola de Cooperacion Internacional [A/5392/06]
Supported (PW12O403-) is a suitable counterion to immobilize chiral azabis(oxazoline)-copper complexes through electrostatic interactions (ion pair formation). Catalytic results are good to excellent in cyclopropanation reactions (up to 97% ee). Partial leaching during recycling when mono-exchanged species are present, favored by strong coordination of by-products, can be minimized by a proper solvent choice and by optimization of the recycling system, allowing the recovery and reuse of the catalyst at least six times without loss of activity and enantioselectivities in the range of 82-96% ee for trans-cyclopropanes. (C) 2010 Elsevier Inc. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据