期刊
JOURNAL OF CATALYSIS
卷 260, 期 1, 页码 1-6出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2008.08.012
关键词
Amine; Gold; Heterogeneous catalysis; Imine; Oxidation; Oxygen
资金
- U.S. Department of Energy [DE-AC02-07CH11358]
Both bulk gold powder (similar to 50 mu m particle size) and alumina-supported gold (50-150 nm) are highly active catalysts for the aerobic oxidative dehydrogenation of amines (CH-NH) to imines (C=N) under the mild conditions of 1 atm O-2 and 100 degrees C. Reactions using the 5% Au/Al2O3 catalyst make efficient use of the gold metal and offer a practical synthesis of imines from amines. These studies add to the growing list of reactions that are catalyzed by bulk gold metal. (C) 2008 Elsevier Inc. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据