期刊
JOURNAL OF BIOSCIENCE AND BIOENGINEERING
卷 115, 期 3, 页码 233-241出版社
SOC BIOSCIENCE BIOENGINEERING JAPAN
DOI: 10.1016/j.jbiosc.2012.10.002
关键词
Supercritical fluid; Carbon dioxide; Biocatalysis; Enzyme; Organic synthesis; Asymmetric synthesis; Candida antarctica lipase B; Novozym 435; Geotrichum candidum; Alcohol dehydrogenase
资金
- Grants-in-Aid for Scientific Research [22550139] Funding Source: KAKEN
The latest advances in biocatalysis using supercritical carbon dioxide (scCO(2)) are reviewed. Stability and stabilization methodologies of enzymes in scCO(2) as well as reactions for organic synthesis are described. Especially, varieties of examples for lipase-catalyzed synthesis of chiral compounds using scCO(2) are given. Furthermore, asymmetric reduction by alcohol dehydrogenase in scCO(2) and carboxylation by decarboxylase in scCO(2) are also introduced. (C) 2012, The Society for Biotechnology, Japan. All rights reserved.
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