期刊
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A
卷 85A, 期 3, 页码 840-846出版社
WILEY-BLACKWELL
DOI: 10.1002/jbm.a.31609
关键词
multifunctional nanocomposites; magnetic nanoparticles; fluorescence quantum dots; sol-gel; thiol coordination
This paper describes a new method for self-assembling multifunctional nanocomposites with a magnetic core of iron oxide Fe3O4 and a shell of CdSe/ZnS quantum dots (QDs). Two sol-gel processes were applied to form the uniform magnetic seeds (Fe3O4@SiO2-SH) and then the thiol coordination was used to bind the CdSe/ZnS QDs to the surface of the seeds. The multifunctional nanocomposites were characterized by means of transmission electron microscopy, X-ray diffraction, energy disperse spectroscopy, fluorescence spectroscopy, infrared spectroscopy, and superconducting quantum interference device (SQUID) magnetometer. The results showed that the magnetic Fe3O4 nanoparticles and the CdSe/ZnS fluorescent QDs were combined together. The nanocomposites were of spherical shape with a mean diameter of 25 nm and exhibited well magnetic response, photostability, chemical activity, and water miscibility. The method put forward here can also be extended to combine systems of other metal oxides and QDs to fabricate core-shell nanocomposites with multifunction for biomedical applications. (c) 2007 Wiley Periodicals, Inc.
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