期刊
JOURNAL OF BIOBASED MATERIALS AND BIOENERGY
卷 2, 期 3, 页码 231-242出版社
AMER SCIENTIFIC PUBLISHERS
DOI: 10.1166/jbmb.2008.411
关键词
Electrospinning; Cellulose Nanofibrils; Poly(vinyl alcohol); Nanofibers
资金
- CNPq
- FINEP
- EMBRAPA-LABEX program (Brazil)
In this work, nanofibers of poly(vinyl alcohol) reinforced with cellulose nanofibrils were produced by electrospinning. The effects of applied voltage, polymer concentration and injection rate, tip-to-collector distance, rotation speed of the collector, and relative humidity on morphology were investigated by scanning electron microscopy. The reinforcing capability of cellulose nanofibrils was investigated by tensile tests. Thermogravimetry, transmission electron microscopy and Fourier transform infrared spectroscopy-attenuated total reflectance analyses were also carried out in order to characterize the presence, orientation and reinforcing effect of the cellulose nanofibrils. Scanning electron microscopy results showed that fiber structure is strongly affected by the electrospinning conditions. Thinner fibers are favored by decreasing viscosity, polymer injection rate, high rotation speed and high relative humidity. Whereas increasing the applied voltage favors the formation of beaded fibers. The reinforced composites had a 2.4-fold increase in their mechanical properties by addition of only 6.6 wt% of cellulose nanofibrils without major changes in elongation at break.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据