期刊
JOURNAL OF APPLIED POLYMER SCIENCE
卷 131, 期 21, 页码 -出版社
WILEY-BLACKWELL
DOI: 10.1002/app.41036
关键词
batteries and fuel cells; coatings; membranes; polyolefins
资金
- Natural Science Foundation Committee [20974094, U1134002]
To effectively improve the affinity of polyethylene (PE) separators with liquid electrolyte without causing a serious pore blockage and to develop a more suitable technology for the industrial production process, porous polyvinylidene fluoride (PVDF) layer-coated PE separators are prepared by the dip-coating method followed by a dry-cast process. Different from previous investigations, a less volatile solvent and a relatively volatile nonsolvent are used to yield a preferable pore structure. A brief introduction on the pore formation mechanism during the dry-cast process is provided. The pore structure of coating layer is found to be successfully controlled by changing evaporation temperature, nonsolvent content, and PVDF concentration. The porous PVDF coating layer-modified separators show better affinity with liquid electrolyte and thermal stability. Especially, the ionic conductivity of the modified separator/liquid electrolyte system with a suitable porous coating layer on the separator could reach two times as that of PE separator/liquid electrolyte system, and the cell assembled with modified PE separator shows better cycle performances. This modification process is proved to be a facile, controllable, and effective method for PE separator modification. Meanwhile, this work could provide some theoretical and technical guidance for the production process. (C) 2014 Wiley Periodicals, Inc.
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