期刊
JOURNAL OF APPLIED POLYMER SCIENCE
卷 129, 期 5, 页码 2435-2442出版社
WILEY-BLACKWELL
DOI: 10.1002/app.38832
关键词
elastomers; self-assembly; supramolecular structures
资金
- National Natural Science Foundation of China [51003032, 51072055, 31201552]
- Fundamental Research Funds for the Central Universities (South China University of Technology) [2009ZM0263, 2012ZZ0016]
- Hesheng Zhujiang Plan Undergraduate Innovative Experiment Project [H11020]
Novel self-healing supramolecular elastomers based on polydimethylsiloxanes (SESi) were synthesized from a mixture of polydimethylsiloxanes derivers with single, di-, or tri-carboxylic acid groups (PDMS-COOHx, where x = 1, 2, and 3, respectively), diethylene triamine, and urea with a two-stage procedure. The reactions and the final products were tracked, characterized, and confirmed by Fourier transform infrared spectroscopy, 1H-NMR, differential scanning calorimetry, dynamic mechanical analysis, and gel permeation chromatography. Compared with a supramolecular rubber based on dimer acid (reported previously) with a similar synthesis procedure, the SESi showed a lower glass-transition temperature of about -113 degrees C for the softer chain of polydimethylsiloxane and showed real rubberlike elastic behavior and self-healing properties at room temperature or even lower temperatures. (c) 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013
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