期刊
JOURNAL OF APPLIED POLYMER SCIENCE
卷 124, 期 3, 页码 2100-2109出版社
WILEY-BLACKWELL
DOI: 10.1002/app.35189
关键词
ethylene-vinyl acetate copolymers; contact angle; XPS; surface free energy; polyolefin
资金
- EC-6th Framework Integrated Project-AMBIO Advanced Nanostructured Surfaces for the Control of Biofouling [NMP4-CT-2005-011827]
Flat and rough thin films were prepared by dip coating using LDPE, PVAc, and EVA polymers containing 1240% VA contents. Surface free energy of flat films was determined by measuring contact angles. Surface atomic composition was investigated by XPS at 0 degrees and 60 degrees take-off angles. XPS results show that hydrophobic PE component was found to enrich at the near-surface region for all EVA samples for a depth of similar to 5 nm for both flat and rough surfaces, whereas hydrophilic VA component was enriched on the surface when VA < 18% for only at 10 nm depth. The difference between the XPS results of the flat and rough surfaces was not significant for EVA samples except EVA-33 surface where the atomic oxygen content decreased 15-20% for rough surfaces. Contact angle hysteresis values for the rough samples were much larger than that of the flat samples for LDPE and EVA-12 surfaces due to the presence of partial trapping of air pockets on these rough surfaces. A good agreement was obtained between surface concentration of atomic oxygen in the 5 nm outermost layer and gamma S- surface free energy component especially for the samples having high VA contents. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012
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