期刊
JOURNAL OF APPLIED POLYMER SCIENCE
卷 121, 期 3, 页码 1506-1511出版社
WILEY
DOI: 10.1002/app.33676
关键词
polyvinyl chloride-supported; pyrrolidine-thiourea; bifunctional organocatalyst; aldol reaction; aqueous medium
资金
- Natural Science Foundation of Henan Province [2008A150003]
Novel polyvinyl chloride (PVC)-supported pyrrolidine-thiourea has been first synthesized in a simple route. The target product was used as a bifunctional organocatalyst for the direct asymmetric aldol reaction between cyclohexanone and arylaldehydes. Effects of solvent and catalyst loading on reaction have been explored. It was found that even at a small dosage of 2.5 mol %, the catalyst exhibited high catalytic activity and stereoselectivities at room temperature in aqueous medium. Additionally, the catalyst can be reused at least for three times. The PVC resin can provide hydrophobic microenvironment for the substrates and catalytic center (pyrrolidine and thiourea moiety) to contact closely. The aldol reaction may take place at the interface between the polymer and aqueous phase. And the results indicated that the thiourea moiety of catalyst had an important effect on the activity and selectivity of the aldol reaction. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 121: 1506-1511, 2011
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