期刊
JOURNAL OF APPLIED POLYMER SCIENCE
卷 116, 期 1, 页码 36-44出版社
WILEY
DOI: 10.1002/app.31452
关键词
rigid poly(vinyl chloride); chemical modification; nucleophilic substitution; thiocyanate; plastic recycling
The reaction of rigid poly(vinyl chloride) (PVC) with iodide, hydroxide, azide, and thiocyanate as nucleophiles (Nu) in ethylene glycol (EG) resulted in the substitution of Cl by No additional to the elimination of HCl, leading to the dehydrochlorination of the rigid PVC. High substitution rates were observed for hydroxide, azide and thiocyanate, while the addition of iodide accelerated predominately the elimination of HCl. The substitution by thiocyanate resulted at 150 degrees C in both thiocyanate and is othiocyanate structures, whereas at 190 degrees C, only isothiocyanate was observed in the polymer. The dehydrochlorination yield increased with an increasing molar SCN/Cl ratio, resulting in a maximum substitution at high molar SCN/Cl ratios. When EG was replaced by diethylene glycol (DEG) as solvent, the dehydrochlorination was found to be accelerated. It was assumed that DEG has a higher compatibility with PVC, making it easier to penetrate the rigid PVC particle. For triethylene glycol (TEG), the rapid dehydrochlorination resulted probably in the coverage of the surface of the PVC particle by methyl methacrylate/butadiene/styrene (MBS), preventing the penetration by the solution. The substitution/dehydrochlorination ratio decreased in the order of EG > DEG > TEG because of the declining polarity of the solvent, stabilizing the activated S(N)2 complex. (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 116: 36-44, 2010
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