期刊
JOURNAL OF APPLIED POLYMER SCIENCE
卷 116, 期 5, 页码 2990-2997出版社
WILEY
DOI: 10.1002/app.31832
关键词
rheology; mechanical properties; strain; stress; structure-property relationship
Rheological properties of fiber/polymer suspensions and dynamic mechanical analysis (DMA) of paper sheets containing the same polymers were measured. Correlations between viscoelastic properties of suspensions and strength of paper sheet are presented. Rheological properties of suspensions of microfibrillar cellulose (MFC) and a set of water soluble polymers were measured. Rheological properties of these complex fluids vary considerably depending on the added polymer. A suspension of fiber and carboxymethyl cellulose (CMC) exhibits a viscosity higher than the sum of the viscosity of the individual components in the suspension. In contrast, when cationic starch (CS) is used together with the fiber, the yielding behavior rather than the viscosity is characteristic of the suspension. Dynamic mechanical properties of paper sheets containing CMC or CS as additives were studied at different humidity levels. Different yielding behavior observed in oscillatory rheology can be correlated with straining behavior in dynamic mechanical properties. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 116: 2990-2997, 2010
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