期刊
JOURNAL OF APPLIED POLYMER SCIENCE
卷 114, 期 4, 页码 2415-2420出版社
WILEY
DOI: 10.1002/app.30720
关键词
unsaturated polyester resin; curing of polymers; differential scanning calorimetry (DSC); kinetics modeling; activation energy
The cure kinetics of medium reactivity unsaturated polyester resin formulated for Liquid Composite Molding process simulation was studied by Differential Scanning Calorimetry (DSC) under isothermal conditions over a specific range of temperature. For isothermal curing reactions performed at 100, 110, and 120 degrees C, several influencing factors were evaluated using the heat evolution behavior of curing process. We propose two- and three-parameter kinetic models to describe the cure kinetics of thermoset resins. Comparisons of the model solutions with Our experimental data showed that the three-parameter model was the lowest parameter model capable of capturing both the degree of cure and the curing rate qualitatively and quantitatively. The model parameters were evaluated by a non-linear multiple regression method and the temperature dependence of the kinetic rate constants thus obtained has been determined by fitting to the Arrhenius equation. (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 114: 2415-2420, 2009
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