Large strain response based on relaxor-antiferroelectric coherence in Bi0.5Na0.5TiO3-SrTiO3-(K0.5Na0.5)NbO3 solid solutions

The effect of (K0.5Na0.5)NbO3 (KNN) addition on the ferroelectric and dielectric behavior of 90Bi(0.5)Na(0.5)TiO(3)-10SrTiO(3) (BNT-ST) lead-free piezoceramics was investigated. Polarization and strain hysteresis loops indicate that a relaxor-antiferroelectric coherence will be produced with the addition of KNN as a replacement for ST up to 5% and the destabilization of the phase coherence is accompanied by an enhancement of the bipolar strain with the increase of temperature, which is similar to 0.37% (corresponding to a large signal d(33)* of similar to 530 pm/V at 90 degrees C) at 5mol.% KNN content. This strain was analyzed as derived from an electrostrictive effect at lower electric fields and a field-induced antiferroelectric-ferroelectric phase transition at higher electric fields. The large polar strain response would be of great interest for environmental friendly high-temperature actuators. (C) 2014 AIP Publishing LLC.