期刊
JOURNAL OF APPLIED PHYSICS
卷 114, 期 5, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.4817524
关键词
-
资金
- Hewlett-Packard company
Lead-free ceramics of composition Bi(Mg1/2Ti1/2)O-3-(Bi1/2K1/2)TiO3-(Bi1/2Na1/2)TiO3 were prepared using solid state synthesis techniques. The dielectric spectra showed a T-max of more than 320 degrees C for all compositions, and the transitions became increasingly diffuse as the Bi(Mg1/2Ti1/2)O-3 content increased. A lower temperature transition, indicating a transformation from an ergodic to a non-ergodic relaxor state, was also seen for all compositions, and this transition temperature decreased as the mole fraction of Bi(Mg1/2Ti1/2)O-3 increased. The composition with 1% Bi(Mg1/2Ti1/2)O-3 showed characteristic ferroelectric-like polarization and strain hysteresis. However, compositions with increased Bi(Mg1/2Ti1/2)O-3 content became increasingly ergodic at room temperature with pinched polarization loops and no negative strain. Among these compositions, the magnitude of d(33)* increased with Bi(Mg1/2Ti1/2)O-3 content, and the composition with 10% Bi(Mg1/2Ti1/2)O-3 exhibited a d(33)* of 422 pm/V. Fatigue measurements were conducted on all compositions and while the 1% Bi(Mg1/2Ti1/2)O-3 composition exhibited a measurable, but small loss in maximum strain after a million cycles; all the other compositions from 2.5% to 10% Bi(Mg1/2Ti1/2)O-3 were essentially fatigue-free. Lastly, optical and alternating current impedance measurements were employed to identify intrinsic conduction as the dominant conduction mechanism. These compositions were also highly insulating with high resistivities (similar to 10(7) Omega-cm) at high temperatures (440 degrees C). (C) 2013 AIP Publishing LLC.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据