期刊
JOURNAL OF APPLIED PHYSICS
卷 110, 期 4, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.3615948
关键词
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资金
- Spanish MALTA [CSD2007-00045]
- Bancaixa Foundation [P11B2009-08]
- Spanish-Brazilian Program [PHB2009-0065-PC]
- Ciencia e Innovacion [CTQ2009-14541-C02]
- Generalitat Valenciana for Prometeo [2009/053]
- Brazilian research financing institution: CAPES
- Brazilian research financing institution: CNPq
- Brazilian research financing institution: FAPESP
By combining experimental techniques such as x-ray diffraction, Fourier transform Raman, ultraviolet-visible, x-ray absorption near edge structure, extended x-ray absorption fine structure spectroscopy, and theoretical models, a general approach to understand the relationship among photoluminescence (PL) emissions and excited electronic states in CaWO4 crystals is presented. First-principles calculations of model systems point out that the presence of stable electronic excited states (singlet) allow us to propose one specific way in which PL behavior can be achieved. In light of this result, we reexamine prior experiments on PL emissions of CaWO4. (C) 2011 American Institute of Physics. [doi:10.1063/1.3615948]
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