期刊
JOURNAL OF APPLIED ELECTROCHEMISTRY
卷 43, 期 9, 页码 865-877出版社
SPRINGER
DOI: 10.1007/s10800-013-0575-9
关键词
Graphene oxide; Reduced graphene oxide; Carbon nanotubes; Electrophoretic deposition (EPD); Nanocomposite
资金
- Australian Research Council (ARC)
- Phayao University
- ARC
- Australian National Fabrication Facility (ANFF)
This paper reports on a facile synthesis method for reduced graphene oxide (rGO)/multi-walled carbon nanotubes (MWNTs) nanocomposites. The initial step involves the use of graphene oxide to disperse the MWNTs, with subsequent reduction of the resultant graphene oxide/MWNTs composites using l-ascorbic acid (LAA) as a mild reductant. Reduction by LAA preserves the interaction between the rGO sheets and MWNTs. The dispersion-containing rGO/MWNTs composites was characterized and electrophoretically deposited anodically onto glassy carbon electrodes to form high surface area films for capacitance testing. Pseudo capacitance peaks were observed in the rGO/MWNTs composite electrodes, resulting in superior performance with capacitance values up to 134.3 F g(-1) recorded. This capacitance value is higher than those observed for LAA-reduced GO (LAA-rGO) (63.5 F g(-1)), electrochemically reduced GO (EC-rGO) (27.6 F g(-1)), or electrochemically reduced GO/MWNTs (EC-rGO/MWNTs) (98.4 F g(-1))-based electrodes.
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