期刊
JOURNAL OF APPLIED ELECTROCHEMISTRY
卷 40, 期 3, 页码 475-483出版社
SPRINGER
DOI: 10.1007/s10800-009-0028-7
关键词
Macrocyclic compound; Electrocatalyst; Metallophthalocyanine; Polypyrrole; Oxygen reduction reaction; Fuel cell
资金
- Hi-tech Research and Development Program of China (863) [2007 AA05Z144]
- Education Ministry of China [20070335003]
- National Natural Science Foundation of China [20976156, 50971114]
Macrocyclic compounds such as metallophthalocyanines demonstrated good catalytic activities toward electrochemical reactions. The characteristics of the central cations in metallophthalocyanines significantly influenced their electrocatalytic activities. Addition of conjugated polymers in electrodes improved the electrocatalytic activity by enhancing the electric conductivity. The electrocatalytic activities of macrocyclic compounds could be further improved by heat treatment. The formation of metallic clusters or metal containing organic fragments after pyrolyzing played an important role in improving electrocatalytic activities of macrocyclic compounds. It was considered that macrocyclic compounds might be functioned as a precursor to obtain well-distributed metallic clusters or metal containing organic fragments.
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