期刊
JOURNAL OF ANTIBIOTICS
卷 61, 期 3, 页码 142-148出版社
JAPAN ANTIBIOTICS RESEARCH ASSOC
DOI: 10.1038/ja.2008.123
关键词
marine-derived fungus; ascochytatin; two-component regulatory system; modified Mosher's method
Ascochytatin, a new spirodioxynaphthalene metabolite produced by a marine-derived fungus, was found from a screening program focused on the bacterial two-component regulatory system. The structure of ascochytatin was determined by spectroscopic methods, including NMR and MS. The relative stereochemistry was determined by an X-ray crystallographic analysis, and the absolute stereochemistry was determined by the modified Mosher's method.
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