Influence of the Nature of Liquid Anion Exchanger on the Selectivity of Anion Selective Electrodes

Selectivity coefficients of ion-selective electrodes on the basis of liquid anion exchangers, a quaternary phosphonium salt, and 20 higher quaternary ammonium and other nitrogen-containing salts differing in the length of hydrocarbon radicals, the nature of the quaternary nitrogen atom, and the presence of polar groups near to the exchange center with respect to 17 mineral, organic, and metal complex anions are presented. The effect of the nature of the anion-exchanger on the anion selectivity is discussed.