期刊
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY
卷 27, 期 4, 页码 577-580出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ja10342g
关键词
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资金
- Angloplatinum Ltd.
- University of Stellenbosch
- NRF
A hyphenated HPLC-ICP-OES method for the direct determination of the metal to ligand mole ratios for the series of individually separated Pt-II/IV chlorido-bromido [PtCl4](2-), [PtCl6](2-) and [PtCl6-nBrn](2-) (n = 0-6) species by simultaneous monitoring of the Pt (177.708 nm), Cl (134.724 nm) and Br (148.845 nm) ICP emissions leads to a novel and unambiguous method of chemical speciation of such Pt-II/IV complexes in acidic aqueous solutions.
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