Some properties of Nd and Er complexes with 1,2,3,4,5,6-benzenehexacarboxylic (mellitic) acid

The influence of synthesis conditions on the structural and thermal properties of solid lanthanide 1,2,3,4,5,6-benzenehexacarboxylates (mellitates) was investigated. The general formula of the complexes is Ln(2)(C12O12)center dot nH(2)O (where Ln = Nd(III) and Er(III), n = 10 for Nd, and n = 14 for Er - mild conditions; n = 6 for Nd and Er - hydrothermal synthesis). They were characterized by elemental analysis, X-ray diffraction methods, IR spectroscopy and thermal analysis methods (TG-DSC and TG-FTIR). The prepared complexes are crystalline but not isostructural. The IR spectra confirm deprotonation of all carboxylic groups in all investigated complexes. Their thermal stability as well as pathway of thermal decomposition differ significantly. (c) 2012 Elsevier B.V. All rights reserved.