期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 590, 期 -, 页码 102-109出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2013.11.087
关键词
Graphene; Reduced graphene oxide; Iron carbide; Magnetic graphene nanocomposites; Supercapacitors
资金
- European project AUTOSUPER-CAP
Reduced graphene oxide/Fe3C hybrids were prepared through Fe-based intercalation of graphite oxide (GtO). Altering pH (acidic to basic) of aqueous GtO dispersion, the immobilization of Fe-based intercalant bearing amino benzoate groups (IFe) was strongly affected following either the nucleophilic substitution (sample: IGO) or ion exchange path (sample: IGO/b). Subsequent pyrolysis of the intercalated materials provided magnetic hybrid materials (samples: r-IGO and r-IGO/b), differing in terms of BET surface area (87 and 163 m(2)/g), magnetization (70 and 43 J/T/kg), resistance (3 and 3.7 Ohm) and capacitance (5 and 17 F/g) correspondingly, displaying both magnetic and supercapacitor behavior. IFe triggered after thermal treatment in vacuum the formation of Fe3C nanoparticles encapsulated in a graphite shell whose incorporation into the multi-layer reduced graphene oxide (GO) matrix provided multi-functional materials. In these materials, aggregation is prevented in two directions: (a) between adjacent Fe3C nanoparticles, since the graphitic shell offers isolation, and (b) between bundles of neighboring multi-layer graphenes, due to Fe3C nanoparticle interference. The graphitic shell assists cohesion of encapsulated Fe3C nanoparticles with the graphene matrix as well as chemical stability, affording thus materials appropriate for a variety of applications. (C) 2013 Elsevier B.V. All rights reserved.
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