期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 575, 期 -, 页码 246-256出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2013.04.001
关键词
Lithium-ion batteries; Lithium alloys; Metal oxides; Electrochemical properties; Lithium storage mechanisms
资金
- National Natural Foundation of China [51025102, 51201151]
- Key Science and Technology Innovation Team of Zhejiang Province [2010R50013]
- Zhejiang Postdoctoral Research Program [Bsh1202051]
- China Postdoctoral Science Foundation [2012M521168]
Lithium alloys and metal oxides have been widely recognized as the next-generation anode materials for lithium-ion batteries with high energy density and high power density. A variety of lithium alloys and metal oxides have been explored as alternatives to the commercial carbonaceous anodes. The electrochemical characteristics of silicon, tin, tin oxide, iron oxides, cobalt oxides, copper oxides, and so on are systematically summarized. In this review, it is not the scope to retrace the overall studies, but rather to highlight the electrochemical performances, the lithium storage mechanism and the strategies in improving the electrochemical properties of lithium alloys and metal oxides. The challenges and new directions in developing lithium alloys and metal oxides as commercial anodes for the next-generation lithium-ion batteries are also discussed. (C) 2013 Elsevier B.V. All rights reserved.
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