期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 522, 期 -, 页码 167-171出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2012.01.143
关键词
VPO4/C; Lithium-ion batteries; Core-shell; Anode materials
资金
- 973 Program in China [2009CB220100]
Pristine VPO4 is a ground-state magnetic semiconductor, disclosed by density functional theory computations; therefore, core-shell VPO4/C composites were proposed and prepared via a sol-gel route. X-ray diffraction confirms the phase of orthorhombic vanadium phosphate, and scanning electron microscopy and transmission electron microscopy show that VPO4 particles are coated with amorphous carbon film of similar to 8 nm in thickness to form core-shell nanostructures. Galvanostatic charge/discharge and cyclic voltammetry tests demonstrate that both the initial and reversible lithium storage capacities of VPO4 were apparently enhanced due to the carbon coating. Core-shell structures can effectively improve the electrochemical performances of phosphate-based Li-ion battery materials. (C) 2012 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据