Composite Li[Li0.11Mn0.57Ni0.32]O2: Two-step molten-salt synthesis, oxidation state stabilization, and uses as high-voltage cathode for lithium-ion batteries

Composite Li[Li0.11Mn0.57Ni0.32]O-2 was initially prepared by a two-step molten-salt method for uses as high-voltage cathode of lithium-ion batteries. This new synthetic route involves a low-temperature melting process of sodium acetate and a second high-temperature melting process of sodium carbonate, which is proved to be advantageous in simplifying the preparation processes of stabilizing oxidation states of framework metal ions at Mn4+ and Ni2+. In particular, the melting temperature of 900 degrees C for the second process is found to be crucial for the formation of the composite. The resultant composite crystallized in a layered structure, and was constructed by particles with dimensions about 100-150 nm. As a consequence of the stabilization of oxidation state and the formation of layered structure, the composite, when acting as a high-voltage cathode for lithium-ion batteries, exhibited a reproducible electro-chemical performance as featured by an initial discharge capacity of 250.8 mAh g(-1) between 4.6 V and 2.0 V and a high cycling ability with little capacity decay at a current density of 20 mAg(-1). (C) 2012 Elsevier B.V. All rights reserved.