期刊
NANOSCALE
卷 7, 期 43, 页码 18278-18283出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5nr05131b
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类别
资金
- NSFC [21072001, 51472001, 21372006, 21373176, 21422305]
- Ministry of Education
- Ministry of Human Resources and Social Security
- Education Department of Anhui Province
- Anhui Province International Scientific and Technological Cooperation Project
- Anhui University
- Scientific Research Fund of Hunan Provincial Education Department [13A100]
We report the X-ray crystallographic structure of an 18-metal atom Au-Ag bimetallic nanocluster (NC) formulated as [Au15Ag3(SC15H11)(14)]. This NC consists of a Au6Ag3 bi-octahedral kernel, which is built up by two octahedral Au3Ag3 units through sharing one Ag3 triangular face. The [Au15Ag3(SC6H11)(14) can be viewed as a core shell structure with the doped Ag atoms as the core and Au atoms as the shell. Detailed analyses by UV-vis spectroscopy, X-ray photoelectron spectroscopy (XPS), and electrochemical measurements clearly show distinct differences in the electronic structure between [Au15Ag3(SC6H11)(14) and the homometal [Au-18(SC6H11)(14)] NC. This study contributes to the deep understanding on bimetallic nanoclusters.
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