期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 509, 期 26, 页码 7205-7209出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2011.04.065
关键词
Li4Ti5O12; Graphene; Lithium-ion battery; Sol-gel; Safety
资金
- National Science Foundation of China [21006033]
- Program for New Century Excellent Talents in Chinese Ministry of Education [NECT-07-0307]
- Fundamental Research Funds for the Central Universities, SCUT [2009220038]
Li4Ti5O12/graphene composite was prepared by a facile sol-gel method. The lattice structure and morphology of the composite were investigated by X-ray diffraction (XRD) and scanning electronic microscopy (SEM). The electrochemical performances of the electrodes have been investigated compared with the pristine Li4Ti5O12 synthesized by a similar route. The Li4Ti5O12/graphene composite presents a higher capacity and better cycling performance than Li4Ti5O12 at the cutoff of 2.5-1.0 V, especially at high current rate. The excellent electrochemical performance of Li4Ti5O12/graphene electrode could be attributed to the improvement of electronic conductivity from the graphene sheets. When discharged to 0V, the Li4Ti5O12/graphene composite exhibited a quite high capacity over 274mAhg(-1) below 1.0 V, which was quite beneficial for not only the high energy density but also the safety characteristic of lithium-ion batteries. (C) 2011 Elsevier B. V. All rights reserved.
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