期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 509, 期 9, 页码 3991-3994出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2010.12.204
关键词
Spent alkaline Zn-Mn batteries; Mn-Zn ferrite nanoparticles; Auto-combustion; Magnetic properties
资金
- National Natural Science Foundation of China [50802008, 50874010, 50972013]
- National Science Foundation
Using spent alkaline Zn-Mn batteries as raw material, Mn-Zn soft magnetic ferrite nanoparticles are prepared by multi-step processes including acid leaching, chemical treatment of battery iron shells and citrate-nitrate precursor auto-combustion. Acid leaching and chemical treatment mechanisms are investigated. Dried gels thermal decomposition process, auto-combustion, phase composition, morphological and magnetic properties of as-prepared Mn-Zn ferrite nanoparticles are characterized by thermogravimetric and differential thermal analysis, X-ray powder diffraction, transmission electron microscopy and vibrating sample magnetometer. Synthesized Mn-Zn ferrite nanoparticles (Mn0.5Zn0.5Fe2O4) have pure ferrite phase, larger saturation magnetization (M-s = 60.62 emug(-1)) and lower coercivity (H-c = 30 Oe) compared with the same composition ferrites prepared by other techniques due to better crystallinity. Mn-Zn ferrite nanoparticles synthesis method presents a viable alternative for alkaline Zn-Mn batteries recycling. (C) 2011 Elsevier B.V. All rights reserved.
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