期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 501, 期 2, 页码 265-268出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2010.04.086
关键词
Diluted magnetic semiconductor; Co-doped ZnO flakes; Room temperature ferromagnetism
资金
- National Natural Science Foundation of China [20471007, 10204003]
A series of high quality Zn1-xCoxO (x <= 0.10) flakes were synthesized by hydrothermal route XRD and TEM characterizations indicate that the as-prepared samples were crystalline with wurtzite structure and no metallic Co or other secondary phases were found. Optical absorption and Raman results further confirm the incorporation of Co2+ ions in the ZnO lattice Magnetic measurements indicate that the Zn1-xCoxO (x <= 0.1) flakes show obvious ferromagnetic characteristics at room temperature. However, at higher doping content of Co2+, the ferromagnetic behavior was suppressed and paramagnetic nature was observed The decrease of ferromagnetism with increasing doping concentration demonstrates that ferromagnetism observed at room temperature is an intrinsic property of Zn1-xCoxO flakes, and does not originate from any secondary phase. (C) 2010 Elsevier B V. All rights reserved
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