4.8 Article

Highly active and durable platinum-lead bimetallic alloy nanoflowers for formic acid electrooxidation

期刊

NANOSCALE
卷 7, 期 11, 页码 4894-4899

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4nr07375d

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资金

  1. National Natural Science Foundation of China [21473111, 21376122, 21273116]
  2. Natural Science Foundation of Jiangsu Province [BK20131395]
  3. United Fund of NSFC
  4. United Fund of Yunnan Province [U1137602]
  5. Industry-Academia Cooperation Innovation Fund Project of Jiangsu Province [BY2012001]
  6. National Basic Research Program of China (973 Program) [2012CB215500]
  7. Fundamental Research Funds for the Central Universities [GK201402016]
  8. National and Local Joint Engineering Research Center of Biomedical Functional Materials
  9. Priority Academic Program Development of Jiangsu Higher Education Institutions

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The Pt84Pb16 (atomic ratio) bimetallic alloy nanoflowers (Pt84Pb16 BANFs) are synthesized by a simple one-pot hydrothermal reduction method that effectively enhance the dehydrogenation pathway of the formic acid oxidation reaction (FAOR) due to the ensemble effect and the electronic effect. As a result, the mass activity of Pt84Pb16 BANFs for the FAOR is 16.7 times higher than that of commercial Pt black at 0.3 V potential.

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