4.8 Article

Nanoparticle mediated micromotor motion

期刊

NANOSCALE
卷 7, 期 11, 页码 4949-4955

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4nr07558g

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资金

  1. National Natural Science Foundation of China [21304064]
  2. Natural Science Foundation of Jiangsu Province [BK20130292]
  3. Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
  4. Fund for Excellent Creative Research Teams of Jiangsu Higher Education Institutions, Jiangsu Key Laboratory for Carbon-Based Functional Materials Devices
  5. SRF for ROCS, SEM
  6. National Science Foundation [CMMI-1100166, DMR-1308958]
  7. Division Of Materials Research
  8. Direct For Mathematical & Physical Scien [1308958] Funding Source: National Science Foundation

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In this paper, we report the utilization of nanoparticles to mediate the motion of a polymer single crystal catalytic micromotor. Micromotors have been fabricated by directly self-assembling functional nanoparticles (platinum and iron oxide nanoparticles) onto one or both sides of two-dimensional polymer single crystals. We show that the moving velocity of these micromotors in fluids can be readily tuned by controlling the nanoparticles' surface wettability and catalytic activity. A 3 times velocity increase has been achieved for a hydrophobic micromotor as opposed to the hydrophilic ones. Furthermore, we demonstrate that the catalytic activity of platinum nanoparticles inside the micromotor can be enhanced by their synergetic interactions with iron oxide nanoparticles and an electric field. Both strategies lead to dramatically increased moving velocities, with the highest value reaching similar to 200 mu m s(-1). By decreasing the nanoparticles' surface wettability and increasing their catalytic activity, a maximum of a similar to 10-fold increase in the moving speed of the nanoparticle based micromotor can be achieved. Our results demonstrate the advantages of using nanoparticles in micromotor systems.

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