期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 484, 期 1-2, 页码 896-901出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2009.05.081
关键词
Nanostructured materials; Coating materials; Thin films; Vapour deposition; EXAFS
资金
- EC [R113-CT-2004-506008]
X-ray absorption fine structure (XAFS) studies of Ni nanograins embedded in carbonaceous films were performed basing on the K edge spectra of nickel. A series of samples containing various doses of Ni doped to the film during the deposition was studied. The crystalline structure and chemical constitution of formed nanograins were found dependent on the nickel dose. They change along the series from those similar to bulk structure of metallic Ni towards amorphous form of NiO. The Fourier transform fitting analysis based on Ni fcc and NiO rock salt models showed for all samples a significant reduction of the range of atomic order around Ni as compared to appropriate bulk materials. The changes in an oxide content rate in the nanograins were evaluated by fitting the coefficients of the linear combination spanned on two the most distinct measured XAFS spectra. We have found that low oxygen inflow resulted in formation of amorphous NiO, but saved the metallic core of grains. High oxygen uptake resulted in thorough grain oxidation. (C) 2009 Elsevier B.V. All rights reserved.
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