期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 485, 期 1-2, 页码 L47-L51出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2009.06.078
关键词
Hydrogen storage; Borohydrides; Dehydriding; Mechanical milling
资金
- CONICET
- ANPCyT [PICT 33387]
- Instituto Balseiro (University of Cuyo)
The synthesis of a new borohydride with a theoretical hydrogen capacity of 6 5 wt% is reported. Both XRD and FTIR studies demonstrate that Ce(BH4)(3) is obtained from mechanochemical reaction between CeCl3 and LiBH4. Dehydriding properties of Ce(BH4)(3) were investigated using XRD, DSC and volumetry using a Sievert-type device. Thermal decomposition of Ce(BH4)(3) led to 3 5 wt% hydrogen release in a multi-step process, involving an unknown intermediate compound and CeH2 It was observed that Ce(BH4)(3) IS partially reversible under 6 MPa of H-2 at 350 degrees C and absorbs 28% of the total hydrogen capacity obtained experimentally. The activation energy of Ce(BH4)(3) decomposition is 136 kJ mol(-1). (C) 2009 Elsevier B.V All rights reserved.
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