期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 481, 期 1-2, 页码 75-80出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2009.03.123
关键词
Diborides; Electronic structure; Magnetic susceptibility; Magnetic anisotropy
The temperature dependencies of the magnetic susceptibility chi and its anisotropy Delta chi = chi - chi were measured for the hexagonal single crystalline TB2 compounds (T = Sc, Ti, Zr, Hf, V and Cr) in the temperature range 4.2-300 K. It was found that Delta chi varies strongly and nonmonotonously with the filling of the hybridized d-band, being almost temperature independent and the largest for the diborides of group 4 metals. Ab initio calculations of the electronic structure and susceptibility of the diborides provide evidence that magnetic anisotropy originates from competing Van Vleck paramagnetism and the orbital diamagnetism of conduction electrons. (C) 2009 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据