期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 485, 期 1-2, 页码 462-466出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2009.05.140
关键词
Lithium/pyrite cell; Pyrite cathode; Electroless nickel plating; Precipitation
资金
- Korea government (MEST) [R01-2008-000-20940-0]
- National Research Foundation of Korea [R01-2008-000-20940-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
The effects of nickel precipitation and the cut-off voltage on the electrochemical properties of a pyrite cathode were investigated by using an electroless nickel-plating method. After nickel precipitation, some nickel particles that were precipitated on the surface of pyrite accumulated between the pyrite powder particles. In the voltage range of 0.4-3.2 V, a cell with nickel-precipitated pyrite exhibited a rapid decrease in discharge capacity and poor columbic efficiency. On the other hand, in the voltage range of 0.8-2 4 V. the cell showed an improved cycle life property and good coulombic efficiency because irreversible reactions below 0.8 V and sulfur oxidation above 2.4 V were suppressed by controlling the cut-off potential and the internal resistance was decreased by nickel precipitation. (C) 2009 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据