4.7 Article

Magnetocaloric effect in 4d itinerant ferromagnet SrRuO3

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JOURNAL OF ALLOYS AND COMPOUNDS
卷 459, 期 1-2, 页码 51-54

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ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2007.05.022

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magnetocaloric effect; phase transition; oxide materials

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The magnetocaloric effect (MCE) in 4d itinerant ferromagnet SrRuO3 prepared by conventional ceramic processing has been investigated using superconducting quantum interference device (SQUID). SrRuO3 material exhibits magnetic entropy change Delta S-M = -2.5 J/kg K and adiabatic temperature change Delta T-ad = 3.1 K at an applied field of 6.5 T and near Curie temperature (similar to 160 K). Based on the analysis of Debye approximation, the lattice entropy change reaches Delta S-L = 0.34 J/kg K and is 12% of total entropy changes. The present work demonstrates the importance of the lattice entropy change in SrRuO3 material with second-order phase transition since the large change in lattice volume exhibits near Curie temperature. (C) 2007 Elsevier B.V. All rights reserved.

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