期刊
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
卷 62, 期 26, 页码 6065-6071出版社
AMER CHEMICAL SOC
DOI: 10.1021/jf5010429
关键词
phloem mobility; glucosyl conjugates; click chemistry; glycosyl azides; glucose positions
资金
- National Natural Science Foundation of China [31171886]
- Doctor Science Research Foundation of the Education Ministry of China [20114404110020]
In our previous work, a glucose fipronil (GTF) conjugate at the C-1 position was synthesized via click chemistry and a glucose moiety converted a non-phloem-mobile insecticide fipronil into a moderately phloem-mobile insecticide. In the present paper, fipronil was introduced into the C-2, C-3, C-4, and C-6 positions of glucose via click chemistry to obtain four new conjugates and to evaluate the effects of the different glucose isomers on phloem mobility. The phloem mobility of the four new synthetic conjugates and GTF was tested using the Ricinus seedling system. The results confirmed that conjugation of glucose at different positions has a significant influence on the phloem mobility of GTF conjugates.
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