期刊
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
卷 61, 期 19, 页码 4585-4592出版社
AMER CHEMICAL SOC
DOI: 10.1021/jf401303q
关键词
soft coral; Sinularia rigida; sinulariols T-Z(5); structural elucidation; antifouling activity
资金
- National Natural Science Foundation of China (NSFC) [30930109]
- National Key Innovation Project [201005022-4]
- [GZ816]
- [2011AA090701]
- [2013AA092902]
- [2010DFA31610]
Chemical examination of the soft coral Sinularia rigida resulted in the isolation of 12 new cembranoids, namely, sinulariols T-Z(5) (1-12), together with a known analogue, 13. Their structures were determined on the basis of ID and 2D NMR (COSY, HSQC, HMBC, and NOESY) spectroscopic analyses in association with MS and IR data. Compounds 7 and 13 showed potent antifouling activity for the inhibition against the barnacle Balanus amphitrite and moderate inhibition against Bugula neritina. The primary structure-activity relationship is discussed.
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