4.7 Article

Radical-Scavenging Compounds from Olive Tree (Olea europaea L.) Wood

期刊

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
卷 62, 期 1, 页码 144-151

出版社

AMER CHEMICAL SOC
DOI: 10.1021/jf403998t

关键词

olive tree wood; Olea europaea; agricultural byproducts; online HPLC-DAD-radical-scavenging technique; (-)-oleuropeic acid; (-)-olivil; aldehydic form of oleuropein aglycone; (+)-1-hydroxypinoresinol 1-O-beta-D-glucopyranoside; (-)-oleuropeic acid 1 '-O-beta-D-glucopyranosyl ester; (-)-oleuropeic acid 6 '-O-alpha-D-glucopyranosyl ester; (-)-oleuropeic acid 6 '-O-beta-D-glucopyranosyl ester; (-)-olivil 4-O-beta-D-glucopyranoside; (-)-perillic acid 1 '-O-beta-D-primeverosyl ester

资金

  1. Spanish Ministerio de Educacion y Ciencia [CTQ2005-07005/PPQ]
  2. FEDER funds of the European Union
  3. Andalusian Government Junta de Andalucia
  4. Centro de Instrumentacion Cientifico-Tecnica of the University of Jaen

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The purpose of this study was to complete knowledge on the chemical composition and radical-scavenging activity of olive tree wood. Two new monoterpene glycosides, (-)-oleuropeic acid 6'-O-alpha-D-glucopyranosyl ester (6a) and (-)-perillic acid 1'-O-beta-6-primeverosyl ester (8), together with the known compounds (-)-oleuropeic acid (1), (-)-olivil (2), the aldehydic form of oleuropein aglycone (3), (+)-1-hydroxypinoresinol 1-O-beta-D-glucopyranoside (4), (-)-oleuropeic acid 1'-O-beta-n-glucopyranosyl ester (5), (-)-oleuropeic acid 6'-O-beta-D-glucopyranosyl ester (6b), and (-)-olivil 4-O-beta-n-glucopyranoside (7) were isolated from an ethyl acetate extract. The radical scavengers found (2-4 and 7) were detected and isolated with the help of the online HPLC-DAD-DPPH/ABTS technique. Compounds 2-4 and 7 displayed a higher antioxidative effect against the free radical DPPH than the reference BHT and lower than hydroxytyrosol, whereas compounds 1, 5, 6a, 6b, and 8 showed no activity.

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